TY  - JOUR
A1  - Biletzki, Tobias
A1  - Görls, Helmar
A1  - Imhof, Wolfgang
T1  - rac-1-(4-tert-Butylphenyl)-5-ethyl-4-ferrocenyl-5-hydroxy-1H-pyrrol-2(5H)-one
T2  - Crystallographic communications
N2  - The title compound, [Fe(C5H5)(C21H24NO2)], which is produced by the oxidation of 1-(4-tert-butylphenyl)-2-ethyl-3-ferrocenylpyrrole, crystallizes as a racemic mixture in the centrosymmetric space group P21/n. The central heterocyclic pyrrole ring system subtends dihedral angles of 13.7 (2)° with respect to the attached cyclopentadienyl ring and of 43.6 (7)° with the major component of the disordered phenyl group bound to the N atom. The 4-tert-butylphenyl group, as well as the non-substituted Cp ring are disordered with s.o.f. values of 0.589 (16) and 0.411 (16), respectively. In the crystal, molecules with the same absolute configuration are linked into infinite chains along the b-axis direction by O—H···O hydrogen bonds between the hydroxy substituent and the carbonyl O atom of the adjacent molecule.
KW  - crystal structure
KW  - pyrrole
KW  - pyrrolone
KW  - ferrocene
Y1  - 2024
UR  - https://uko.opus.hbz-nrw.de/frontdoor/index/index/docId/2477
UR  - https://nbn-resolving.org/urn:nbn:de:hbz:kob7-24777
SP  - 264
EP  - 266
ER  -